Paper from Cotton Linters as Substrate for Ammonia Nanosensor using Electrospun Alginate Nanofibers


Keywords:
Cellulosic paper, Cotton linters, Electrospinning, Nanofibres, NanosensorAbstract
Nanosensor to detect ammonia was produced using electrospun nanofibers of sodium alginate (SA) blended with poly (vinyl alcohol) (PVA) by adding pH indicator dyes. During electrospinning, nanofibers were collected on a cellulosic paper prepared from cotton linters, at a flow rate of 0.5 mL/h, 15 kV voltage and 15 cm spinneret tip to collector distance. The conductivity and viscosity of the solutions were measured to understand the effect of pH indicator dyes in the solutions used for electrospinning. Optical microscopy, SEM and AFM analyses were performed to evaluate the morphology of nanofiber mats. The pH indicator dye loaded nanofiber mats were characterized by UV–visible spectroscopy, dye leaching test, contact angle measurement and CIE color space analyzer. This flexible nanosensor prepared on paper substrate can find potential application in various fields like smart fish packaging, human breath analysis and agriculture as it can help to determine the nature of soil.Downloads
References
Anwane, R. S., Kondawar, S. B. and Late, D.J. (2018) – Bessel’s polynomial fitting for electrospun polyacrylonitrile/polyaniline blend nanofibers based ammonia sensor – Materials Letters, 221: 71-73.
Christopher, A. B., Melissa, D. K., Carl, D. S., Sung, I. J., Kimberly, L. S., Eben, A., Saad, A. K. (2011) – Electrospinning alginate-based nanofibers: From blends to crosslinked low molecular weight alginate-only systems – Carbohydrate Polymers, 85: 111–119.
Crowley, K., Pacquit, A., Hayes, J., King, T. L. and Diamond, D. (2005) – A Gas-Phase Colorimetric Sensor for the Detection of Amine Spoilage Products in Packaged Fish – SENSORS, 2005 IEEE (doi: 10.1109/ICSENS.2005.1597809).
Duchesne, L. C. and Larson, D. W. (1989) – Cellulose and the Evolution of Plant Life – BioScience, 39: 238-241.
Hedwig, R., Lahna, K., Idroes, R., Karnadi, I., Tanra, I., Iqbal, J., Kwaria, D., Kurniawan, D.P., Kurniawan, K.H. and Tjia, M.O. (2019) – Food analysis employing high energy nanosecond laser and low pressure He ambient gas – Microchem. J, 147: 356–364.
Huarong, N., Aihua, H., Wanling, W., Jianfen, Z., Shanshan, X., Junxing, L., Charles, C. H. (2009) – Effect of poly(ethylene oxide) with different molecular weights on the electrospinnability of sodium alginate – Polymer, 50: 4926–4934.
Jian-Wei, L., Yong-Liang, Z., Zhao-Xia, G., Ping, H. and Jian, Y. (2006) – Electrospinning of sodium alginate with poly(ethylene oxide) – Polymer, 47: 802.
Kriegel, C., Arrechi, A., Kit, K., McClements, D.J. and Weiss, J. (2008) – Fabrication, Functionalization, and Application of Electrospun Biopolymer Nanofibers – Critical Reviews in Food Science and Nutrition, 48: 775-797.
Schiffman, J. D. and Schauer, C. L. (2008) – A Review: Electrospinning of Biopolymer Nanofibers and their Applications – Polymer Reviews, 48: 317-352.
Schuerena L. V., Thierry, D. M., Iline, S., Özgür, C., Karen, H., Veronique, V. S. and Karen, D. C. (2013) – Polycaprolactone and polycaprolactone/chitosan nanofibres functionalised with the pH-sensitive dye Nitrazine Yellow – Carbohydrate Polymers, 91(1): 284-293.
Wells, N., Yusufu, D. and Mills, A. (2019) - Colourimetric plastic film indicator for the detection of the volatile basic nitrogen compounds associated with fish spoilage – Talanta, 194: 830-836.
Xiaochuang, S., Yanjun T., Dingding Z., Junhua Z., Daliang G. and Gustavo F. (2016) – Improving the electroconductivity and mechanical properties of cellulosic paper with multi-walled carbon nanotube/polyaniline nanocomposites – Journal of Bioresources and Bioproducts, 1(1): 48-54.
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