Double-boiled linseed and mustard oil-based formulations to prepare oil-coated controlled release fertilizers


308 / 300

Authors

  • ABHIJIT SARKAR ICAR-Indian Institute of Soil Science, Bhopal
  • DIPAK RANJAN BISWAS ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India
  • SAMAR CHANDRA DATTA ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India
  • BRAHMA SWARUP DWIVEDI ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India
  • RAJESH KUMAR ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India
  • KALI KINKAR BANDYOPADHYAY ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India
  • RANJAN BHATTACHARYYA ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India
  • MADHUMONTI SAHA ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India
  • SIDDHARTHA SANKAR BISWAS ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India
  • ASHOK KUMAR PATRA ICAR-Indian Agricultural Research Institute, New Delhi 110 012, India

https://doi.org/10.56093/ijas.v91i2.111645

Keywords:

Controlled release fertilizers, Diammonium phosphate, Korsmeyer-Peppas model, Linseed oil, Mustard oil

Abstract

Controlled nutrient release is one of the best fertilizer management options to enhance nutrient recovery efficiency and minimize environmental pollution. The research was conducted at Division of Soil Science and Agricultural Chemistry, ICAR-Indian Agricultural Research Institute, New Delhi during 2019-20 with the aims to formulate four oil-based formulations from different combinations of double-boiled linseed (Linum usitatissimum) and mustard (Brassica juncea) oils for coating diammonium phosphate (DAP) and to assess nitrogen (N) and phosphorus (P) release from them against uncoated DAP. Results revealed that oil-based formulation with 100 wt% linseed oil (Oil- 4 formulation) showed maximum variation in weight over the 30 days of curing; whereas, oil-based formulation containing 25 wt% linseed oil + 75 wt% mustard oil (Oil-1 formulation) had lowest variation in weight during curing. The N and P release pattern from oil-based formulations of coated DAP over 30 days in water medium with reference to uncoated DAP revealed that Oil-1 coated DAP formulation released lesser quantities of N and P than Oil-2 coated DAP; while 8% levels of coating material released lesser N and P than the 4% levels of coating. Compared to First-order kinetics model, the N and P release data were better fitted to Korsmeyer-Peppas model, which revealed that nutrient release from uncoated DAP followed Quasi-Fickian diffusion. Except 8%-Oil-2-DAP, all the oil-based formulations of coated DAP followed anomalous (Non-Fickian) diffusion. Thus, it may be concluded that double-boiled linseed and mustard oil-based formulations (Oil-1 formulation) of coated DAP could be an alternative option to produce cost effective controlled release fertilizers.

Downloads

Download data is not yet available.

References

Bortoletto-Santos R, Guimarães G G F, Roncato Junior V, da Cruz D F, Polito W L and Ribeiro C. 2020. Biodegradable oil-based polymeric coatings on urea fertilizers: N release kinetics and transformation of urea in soil. Scientia Agricola, DOI: http://dx.doi.org/10.1590/1678-992X-2018-0033 DOI: https://doi.org/10.1590/1678-992x-2018-0033

Bortoletto-Santos R, Ribeiro C and Polito W L. 2016. Controlled release of nitrogen-source fertilizers by natural-oil-based poly (urethane) coatings: The kinetic aspects of urea release. Journal of Applied Polymer Science 43790: 1–8. DOI: https://doi.org/10.1002/app.43790

Jackson M L. 1973. Methods of Chemical Analysis. Prentice Hall of India (Pvt) Ltd, New Delhi, India.

Juita, Dlugogorski B Z, Kennedy E M and Mackei J C. 2012. Low temperature oxidation of linseed oil: a review. Fire Science Reviews 1: 1–36. DOI: https://doi.org/10.1186/2193-0414-1-3

Korsmeyer R W and Peppas N A. 1984. Solute and penetrant diffusion in swellable polymers. III. Drug release from glassy poly(HEMA-co-NVP) copolymers. Journal of Controlled Release 1: 89–98. DOI: https://doi.org/10.1016/0168-3659(84)90001-4

Roy T, Biswas D R, Datta S C and Sarkar A. 2018a. Phosphorus release from rock phosphate as influenced by organic acid loaded nanoclay polymer composites in an Alfisol. Proceedings of National Academy of Sciences, India Section B: Biological Science 88: 121–32. DOI: https://doi.org/10.1007/s40011-016-0739-6

Roy T, Biswas D R, Datta S C, Sarkar A and Biswas S S. 2018b. Citric acid loaded nano clay polymer composite for solubilization of Indian rock phosphates: A step towards sustainable and phosphorus secure future. Archives of Agronomy and Soil Science 64: 1564–81. DOI: https://doi.org/10.1080/03650340.2018.1444275

Roy T, Biswas D R, Datta S C, Dwivedi B S, Lata, Bandyopadhyay K K, Sarkar A, Agarwal B K and Shahi D K. 2015. Solubilization of Purulia rock phosphate through organic acid loaded nanoclay polymer composite and phosphate solubilizing bacteria and its effectiveness as P-fertilizer to wheat. Journal of the Indian Society of Soil Science 63: 327–38. DOI: https://doi.org/10.5958/0974-0228.2015.00043.2

Sarkar A, Biswas D R, Datta S C, Manjaiah K M and Roy T. 2017. Release of phosphorus from laboratory made coated phosphatic fertilizers in soil under different temperature and moisture regimes. Proceedings of National Academy of Sciences, India Section B: Biological Science 87: 1299–1308. DOI: https://doi.org/10.1007/s40011-015-0693-8

Sarkar A, Biswas D R, Datta S C, Roy T, Biswas S S, Ghosh A, Saha M, Moharana P C and Bhattacharyya R. 2020. Synthesis of poly(vinyl alcohol) and liquid paraffin based controlled release nitrogen-phosphorus formulations for improving phosphorus use efficiency in wheat. Journal of Soil Science and Plant Nutrition. doi: 10.1007/s42729-020-00249-3 DOI: https://doi.org/10.1007/s42729-020-00249-3

Sarkar A, Biswas D R, Datta S C, Roy T, Moharana P C, Biswas S S and Ghosh A. 2018. Polymer coated novel controlled release rock phosphate formulations for improving phosphorus use efficiency by wheat in an Inceptisol. Soil and Tillage Research 180: 48−62. DOI: https://doi.org/10.1016/j.still.2018.02.009

Sarkar A, Biswas D R, Datta S C, Dwivedi B S, Bhattacharyya R, Kumar R, Bandyopadhyay K K, Saha M, Chawla G, Saha J K and Patra A K. 2021. Preparation of novel biodegradable starch/poly(vinyl alcohol)/bentonite grafted polymeric films for fertilizer encapsulation. Carbohydrate Polymers. https:// doi.org/10.1016/j.carbpol.2021.117679 DOI: https://doi.org/10.1016/j.carbpol.2021.117679

Sarkar S, Datta S C and Biswas D R. 2015. Effect of fertilizer loaded nanoclay/superabsorbent polymer composites on nitrogen and phosphorus release in soil. Proceedings of National Academy of Sciences, India Section B: Biological Science 85: 415–21. DOI: https://doi.org/10.1007/s40011-014-0371-2

Scrimgeour C. 2005. Chemistry of Fatty Acids. Shahidi F (Eds), Bailey’s Industrial Oil and Fat Products (6th Eds). John Wiley and Sons, Inc, pp 1–44. DOI: https://doi.org/10.1002/047167849X.bio005

Suri V K and Datta B. 1995. Linseed oil coated urea and ammelide as slow release nitrogenous fertilizers. Journal of the Indian Society of Soil Science 43: 615–18.

Svane P. 2006. Determination of changes in mass and volume of linseed oil during drying. Surface coatings International Part B: Coatings Interfaces 89: 327–31. DOI: https://doi.org/10.1007/BF02765585

Trenkel M E. 2010. Slow- and controlled-release and stabilized fertilizers: an option for enhancing nutrient use efficiency in agriculture. International Fertilizer Industry Association Paris, France.

UN. 2013. World Population Projected to Reach 9.6 Billion by 2050. United Nations (UN), Department of Economy and Social Affairs, Rome, Italy.

Downloads

Submitted

2021-04-08

Published

2021-04-08

Issue

Section

Articles

How to Cite

SARKAR, A., BISWAS, D. R., DATTA, S. C., DWIVEDI, B. S., KUMAR, R., BANDYOPADHYAY, K. K., BHATTACHARYYA, R., SAHA, M., BISWAS, S. S., & PATRA, A. K. (2021). Double-boiled linseed and mustard oil-based formulations to prepare oil-coated controlled release fertilizers. The Indian Journal of Agricultural Sciences, 91(2), 310–314. https://doi.org/10.56093/ijas.v91i2.111645
Citation