Relationship between dichromate oxidizable and total soil organic carbon and distribution of different pools of organic carbon in Vertisols of Central India

Abstract

Geo-referenced soil samples (0-15 cm) were collected from the farmers fields of Sehore (n = 120) and Vidisha (n = 156) district representing AESR 10.1 to establish the relationship between oxidizable SOC and total SOC in Vertisols of Central India and also to study the distribution of different pools of SOC as well as their relationship with crop yield. Total SOC was apportioned into different pools by using 5, 10 and 20 ml of concentrated H₂SO₄ that resulted in 3 acid-aqueous solution ratio of 0.5:1, 1:1 and 2:1. Also crop yields during the following winter season and rainy season from the geo-reference fields were recorded and were transformed to % relative yield. Oxidizable SOC (y) was related to total SOC (x) in the form of y = 0.825x – 0.086 (R₂ = 0.958, n = 276), indicating that oxidizable SOC comprised 82.5% of the total SOC. Therefore it was recommended that a correction factor of 1.21 should be used to convert oxidizable SOC values to get the estimate of total SOC. The mean crop productivity was better related to oxidizable SOC (r = 0.5275) as compared to total SOC(r = 0.4886). The threshold and optimum values of oxidizable SOC were 3.2 and 11.2 g C/kg, respectively, whereas the threshold and optimum values for total SOC were 3.87 and 14.1 g C/kg, respectively. Among the different pools, less labile C was highly correlated (r = 0.5871) with the crop productivity, the computed threshold and optimum value for less labile C were 1.53 and 5.2 g C/kg, respectively.