Application of arjuna (Terminalia Arjuna) bark for adsorptive removal of cadmium (II) ions from simulated water

Cadmium ions removal using arjuna bark biosorbent


252 / 71

Authors

  • Sachin Kumari Department of Chemistry,Chaudhary Charan Singh Haryana Agricultural University, Hisar- 125004, Haryana, India
  • Sushila Singh Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar- 125004, Haryana, India
  • Indu Rani Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar- 125004, Haryana, India
  • Vinod Sangwan Department of Biochemistry, Sher-e-Kashmir University of Agricultural Sciences and Technology of Jammu – 180009, Jammu and Kashmir,India
  • Ram Prakash Department of Soil Sciences, Chaudhary Charan Singh Haryana Agricultural University,Hisar-125004, Haryana, India

https://doi.org/10.56093/jsswq.v16i3.152463

Abstract

The goal of this study was to prepare affordable, easily accessible, and ecologically friendly adsorbent from arjuna (Terminalia arjuna) bark and used to remove cadmium ions from simulated water. To study the influence of various experimental variables such as pH (2–8), adsorbent dose (0.01–0.04 g/50mL cadmium solution), contact time (10–100 min), and initial metal concentration (10–100 mg/L); batch experiments were performed. The characterization of the adsorbent was carried out using energy-dispersive X-ray (EDX), field emission scanning electron microscopy (FESEM), and Fourier-transform infrared spectroscopy (FTIR). Utilising atomic absorption spectroscopy (AAS), the concentration of Cd(II) in an aqueous solution was determined. The arjuna bark adosorbent showed the maximum removal capacity of 72% at optimized pH 6. The experimental data revealed that Freundlich isotherm model fitted well as compared to Langmuir model. The positive ΔH indicates that the adsorption of Cd(II) was endothermic. The present study demonstrated that treated powdered Arjuna bark adsorbent could effectively remediate cadmium ions contaminated water.

Downloads

Download data is not yet available.

Author Biography

  • Sachin Kumari, Department of Chemistry,Chaudhary Charan Singh Haryana Agricultural University, Hisar- 125004, Haryana, India

    Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-   125004, Haryana, India

References

Afroz S and Sen T K (2018) A review on heavy metal ions and dye adsorption from water by agricultural solid waste adsorbents. Water Air Soil Pollutions 229(7):1-50.

Azimi A, AzariA,Rezakazemi Mand Ansarpour M (2017). Removal of Heavy Metals from Industrial Wastewaters: A Review. Chemical and biochemical engineering reviews 4: 37-59.

Daniel M, Nomso C, Hintsho-Mbita and Mabuba N (2022) Diethylamine functionalised Moringa oleifera leaves for the removal of chromium(VI) and bacteria from wastewater.International Journal of Environmental Analytical Chemistry 102(13):3002-3022.

DasJ, SahaR, Nath H, MondalM andNag S (2022) An eco‑friendly removal of Cd(II) utilizing banana pseudo‑fiber and Moringa bark as indigenous green adsorbent and modelling of adsorption by artificial neural network.Environmental Science and Pollution Research 29:86528–86549.

Ezeonuegbu B A, Machido D A,Whong C M Z, Japhet W S, A. Alexiou A, Elazab S T, Qusty N, Yaro C Aand Batiha G E-S (2021) Agricultural waste of sugarcane bagasse as efficient adsorbent for lead and nickel removal from untreated wastewater: biosorption, equilibrium isotherms, kinetics and desorption studies. Biotechnology Reports 30: 614-630.

Fawzy M, Nasr M, Adel S, Nagy H, and Helmi S (2016) Environmental approach and artifcial intelligence for Ni(II) and Cd(II) biosorption from aqueous solution using Typha domingensis biomass. Ecological engineering 95:743–752.

Fertu D L, Bulgariu L and Gavrilescu M (2018) Modeling and optimization of heavy metals biosorption by low-cost sorbents using response surface methodology. Processes 10:523-538.

Freundlich HMF (1906) Over the adsorption in solution. The Journal of Physical Chemistry 57:385–470.

Gurer A G, Aktas K, Akcetin M O, Unsar A E & Asilturk M (2021) Adsorption isotherms, thermodynamics, and kinetic modeling of methylene blue onto novel carbonaceous adsorbent derived from bitter orange peels, Water Air Soil Pollution 232: 138-149.

Iqbal M, Saeed M Aand Zafar S I (2009) FTIR spectrophotometry, kinetics and adsorption isotherms modelling, ion exchangeand EDX analysis for understanding the mechanism of Cd 2+and Pb2+ removal by mango peel waste. Journal of Hazardous Materials164:161-171

Jalbani N, and Soylak M (2014) Ligand less surfactant mediated solid phase extraction combined with Fe3O4 nano-particle for the preconcentration and determination of cadmium and lead in water and soil samples followed by flame atomic absorption spectrometry: multivariate strategy. Ecotoxicology and environmental safety 102: 174-178.

Janani R, Gurunathan B,Sivakumar K, VarjaniS, Ngo H H and Gnansounou E (2022) Advancements in heavy metals removal from effluents employing nano-adsorbents: way towards cleaner production. Environmental Research 203: 815-830.

Joshi S, Kataria N, Garg V Kand Kadirvelu K (2020) Pb2+ and Cd2+ recovery from water using residual tea waste and SiO2@TW nanocomposite. Chemosphere 257: 277-285.

Kataria N and Garg V K (2018) Green synthesis of Fe 3 O 4 nanoparticles loaded sawdust carbon for cadmium (II) removal from water: Regeneration and mechanism. Chemosphere 208:818-828.

Kayan G O and Kayan A (2021) Composite of natural polymers and their adsorbent properties on the dyes and heavy metal ions. Journal of Polymer. Environment 29(11): 3477-3486.

Kumari S, Singh S, Sangwan V and Rani I (2024) Terminalia arjuna Bark Biosorbent for Efficient Lead (II) Removal from Synthetic Wastewater. Journal of Scientific Research and Reports 30(6): 764–772.

Lakherwal D (2014) Adsorption of heavy metals: a review. International journal of environmental 4: 41-48.s

Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of American Chemical Society 40:1361–1403.

Lim AP and ArisA Z (2014) A review on economically adsorbents on heavy metals removal in water. Reviews in Environmental Science and Bio Technology 13(2):163-181.

Madadgar S, Ardejani F D, Boroumand F, Taherdangkoo Z R, and Butscher C (2023). Biosorption of Aqueous Pb (II), Co (II), Cd (II) and Ni (II) Ions from Sungun Copper Mine Wastewater by Chrysopogonzizanioides Root Powder. Minerals13(1): 106.

Mukherjee S, Kumari D, Joshi M, An A Kand Kumar M (2020). Low-cost bio-based sustainable removal of lead and cadmium using a polyphenolic bioactive Indian curry leaf (Murrayakoengii) powder. International Journal of Hygiene and Environmental Health 226: 471-484.

Nag S, Mondal Aand Roy D N (2018) Sustainable bioremediation of Cd (II) from aqueous solution using natural waste materials: kinetics, equilibrium, thermodynamics, toxicity studies and GAANN hybrid modelling. Environmental Technology & Innovation 11:83-104.

Oliveira M R F, Vale Abreu, RomaoK, Carrilho A L E, and Alves C R (2021) Carnauba (Copernicia prunifera) palm tree biomass as adsorbent for Pb(II) and Cd(II) from water medium. Environmental Science and Pollution Research 28(15): 18941–18952.

Rezania S, Taib S M, Din MFM, Dahalan FA and Kamyab H (2016) Comprehensive review on phytotechnology: heavy metals removal by diverse aquatic plants species from wastewater. Journal of hazardous materials 318: 587-599.

Samimi M and Safari M (2022) TMU-24 (Zn-based MOF) as an advance and recyclable adsorbent for the efficient removal of eosin B: characterization, equilibrium, and thermodynamic studies. Environmental Progress & Sustainable Energy, 1–9.

Staron P, Chwastowski J, Banach M (2017) Sorption and desorption studies on silver ions from aqueous solution by coconut fiber. The Journal of Cleaner Production 149:290–301.

Tomar V, Prasad S, Kumar D (2014)Adsorptive removal of fluoride from aqueous media using Citrus limonum (lemon) leaf. Microchemical Journal 112:97-103.

Umeh CT, Nduka JK, Mogale R, Akpomie KG, Okoye NH (2024) Acid-activated corn silk as a promising phytosorbent for uptake of Malachite green and Cd (II) ion from simulated wastewater: equilibrium, kinetic and thermodynamic studies.International Journal of Phytoremediation 26(10):1593-1610.

Wan S, Z. Ma Y, Xue M, Ma S, Xu L,and Qian Q (2014) Sorption of Lead (II), Cadmium(II), and Copper(II) Ions from Aqueous Solutions Using Tea Waste. Industrial & Engineering Chemistry Research 53(9): 3629–3635.

Wang C, Xiong C, He Y, Yang C, Li X, Zheng J, and Wang S (2021). Facile preparation of magnetic Zr-MOF for adsorption of Pb (II) and Cr (VI) from water: Adsorption characteristics and mechanisms. Chemical Engineering Journal 415: 923-928.

Yashni G, Al-Gheethi A, Mohamed R M S R, Shanmugan V A, Abu Bakar J (2021) Characterization of Coriandrum sativum leaves as a sustainable green biosorbent. Materials Today 47(6):1345-1349.

Downloads

Submitted

2024-06-06

Published

2024-12-31

Issue

Section

Articles

How to Cite

Kumari, S. ., Singh, S. ., Rani, I., Sangwan, V. ., & Prakash, R. . (2024). Application of arjuna (Terminalia Arjuna) bark for adsorptive removal of cadmium (II) ions from simulated water: Cadmium ions removal using arjuna bark biosorbent. Journal of Soil Salinity and Water Quality, 16(3), 370-377. https://doi.org/10.56093/jsswq.v16i3.152463