Detection of hydrogenated vegetable oils (vanaspati) in ghee using infrared spectroscopy


605 / 208

Authors

  • ARUN KUMAR Assistant Professor, Department of Dairy and Food Chemistry, College of Dairy and Food Science Technology, Maharana Pratap University of Agriculture and Technology, Udaipur, Rajasthan
  • DARSHAN LAL Retd. Principal Scientist, ICAR-National Dairy Research Institute, Karnal 132 001 Haryana
  • RAMAN SETH Principal Scientist, ICAR-National Dairy Research Institute, Karnal 132 001 Haryana

https://doi.org/10.56093/ijans.v89i7.92053

Keywords:

Adulteration, Ghee, Hydrogenated vegetable oils, IR spectroscopy, Vanaspati

Abstract

Infrared spectroscopy, widely used for the characterization of cis- and transisomers of oils and fats, was used for the detection of adulteration in ghee with hydrogenated vegetable oils (Vanaspati) as the latter contains significantly higher levels of trans isomers formed during hydrogenation process used for vanaspati manufacturing. The average content of trans isomers (expressed as % trielaidin) in buffalo ghee, cow ghee and vanaspati as determined using infrared (IR) absorption at 10.36 μ (965.25/cm) was 5.41, 6.82 and 37.05%, respectively. On the basis of increased level of trans isomers in ghee, as low as 5% addition of vanaspati to ghee could be detected easily.

Downloads

Download data is not yet available.

References

BIS. 1981. Handbook of Food Analysis. SP-18, Part XI-Dairy Products. Bureau of Indian Standards, Manak Bhavan, New Delhi.

Chahine M H, Cousins E R and Feuge R O. 1958. Positional isomers formed during hydrogenation of cottonseed oil. Journal of American Oil Chemists Society 35: 396–401. DOI: https://doi.org/10.1007/BF02632554

Das S, Goswami B and Biswas K. 2016. Milk adulteration and detection: A Review. Sensor Letter 14(1): 4–18. DOI: https://doi.org/10.1166/sl.2016.3580

Firestone D and Villadel-mar M D L. 1961. Determination of isolated trans unsaturation by infra-red spectrophotometry. DOI: https://doi.org/10.1093/jaoac/44.3.459

Journal of Association of Official Agricultural Chemists 44(3): 459–64.

Food Safety Standards Authority of India (FSSAI). 2011. Food Safety and Standards Act 2006 Rules and Regulations. Commercial Law Publishers Pvt. Ltd., New Delhi.

Fox P F and McSweeney P L H. 2015. Dairy Chemistry and Biochemistry. Springer International Publishing, Switzerland. Gandhi K and Lal D. 2017. Butyro-Refractometer (BR) reading linked with solvent fractionation technique as an aid to detect adulteration of palm olein and sheep body fat in ghee. Indian Journal of Natural Products Resources 8(3): 276–28.

Gandhi K, Rana S and Kumar H. 2018. Solvent fractionation technique paired with complete liquefaction time (CLT) test to detect bland of palm olein and sheep body fat in ghee. International Journal of Chemical Studies 6(2): 458–63.

Kumar A, Lal D, Seth R and Sharma R. 2002. Recent trends in detection of adulteration in milk fat – A Review. Indian Journal of Dairy Science 55(6): 319–30.

Kumar A, Lal D, Seth R and Sharma V. 2005. Turbidity test for detection of liquid paraffin in ghee. Indian Journal of Dairy Science 58(4): 298.

Kumar A, Lal D, Seth R and Sharma V. 2009. Apparent solidification time test for detection of foreign oils and fats adulterated in clarified milkfat, as affected by season and storage. International Journal of Dairy Technology 62: 33– 38. DOI: https://doi.org/10.1111/j.1471-0307.2008.00448.x

Kumar A, Lal D, Seth R and Sharma V. 2010. Detection of milk fat adulteration with admixture of foreign oils and fats using a fractionation technique and apparent solidification time test. International Journal of Dairy Technology 63(3): 457–62. DOI: https://doi.org/10.1111/j.1471-0307.2010.00562.x

Kumar A, Upadhyay N, Gandhi K, Naik S N and Sharma V. 2017. Detection of adulteration in anhydrous milk fat (ghee) using season variation in Butyro-refratometer reading studied by employing dry fractionation technique. Indian Journal of Dairy Science 70(5): 563–70.

Navale D and Gupta S. 2016. Detection of adulteration present in milk products. International Journal of Latest Technology in Engineering, Management and Applied Science 6(5): 103–105.

Downloads

Submitted

2019-07-26

Published

2019-07-26

Issue

Section

Articles

How to Cite

KUMAR, A., LAL, D., & SETH, R. (2019). Detection of hydrogenated vegetable oils (vanaspati) in ghee using infrared spectroscopy. The Indian Journal of Animal Sciences, 89(7), 791–794. https://doi.org/10.56093/ijans.v89i7.92053
Citation